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LiMPO4 and Li2MPO4F cathode materials: synthesis, morphology and electrochemical characteristics

Larisa S. Pershina, Efim D. Lyalin, Eugenia A. Ilyina

Abstract


The cathode is one of the key components responsible for the capacity of a lithium-ion battery. The presented review examines structural features and electrochemical characteristics of LiMPO4 and Li2MPO4F materials. In the literature, prototypes of lithium all-solid-state batteries only with LiFePO4 and lithium-ion solid electrolytes have been presented and studied. These cells show capacities in the range from 100 to 160 mA · h/g, which is comparable to lithium-ion batteries with liquid electrolyte. Li2MPO4F cathodes possess a high theoretical capacity of ~ 280 m · Ah/g and a theoretical energy density of ~ 1435 W · h/kg. However, the electrochemical study of Li2MPO4F fluorophosphates is limited due to the lack of a high-voltage liquid or polymer electrolyte. Thus, Li2MPO4F can be considered as a promising cathode for all-solid-state batteries with solid electrolytes that have a wider window of electrochemical stability.

Keywords


cathode material; LiMPO4; Li2MPO4F; solid electrolyte; all-solid-state battery

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References


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DOI: https://doi.org/10.15826/elmattech.2026.5.068

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